Email this article Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles
- Authors: Mikherdov A.S.1, Orekhova Y.A.1, Boyarskii V.P.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 88, No 10 (2018)
- Pages: 2119-2124
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222478
- DOI: https://doi.org/10.1134/S1070363218100158
- ID: 222478
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Abstract
The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl2(CNXyl)2], Xyl = 2,6-Me2C6H3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.
About the authors
A. S. Mikherdov
St. Petersburg State University
Email: v.boiarskii@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
Yu. A. Orekhova
St. Petersburg State University
Email: v.boiarskii@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
V. P. Boyarskii
St. Petersburg State University
Author for correspondence.
Email: v.boiarskii@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
