Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

M. A. Kinzhalov; M. V. Kashina; A. S. Mikherdov; S. A. Katkova; V. V. Suslonov

doi:10.1134/S107036321806021X

Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

作者: Kinzhalov M.¹, Kashina M.¹, Mikherdov A.¹, Katkova S.¹, Suslonov V.¹
隶属关系:
1. St. Petersburg State University
期: 卷 88, 编号 6 (2018)
页面: 1180-1187
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222252
DOI: https://doi.org/10.1134/S107036321806021X
ID: 222252

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Phosphine isocyanide complexes cis-[PtCl₂(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and ¹H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.