Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions
- Autores: Kinzhalov M.1, Kashina M.1, Mikherdov A.1, Katkova S.1, Suslonov V.1
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Afiliações:
- St. Petersburg State University
- Edição: Volume 88, Nº 6 (2018)
- Páginas: 1180-1187
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222252
- DOI: https://doi.org/10.1134/S107036321806021X
- ID: 222252
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Resumo
Phosphine isocyanide complexes cis-[PtCl2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.
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Sobre autores
M. Kinzhalov
St. Petersburg State University
Autor responsável pela correspondência
Email: m.kinzhalov@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. Kashina
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Mikherdov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
S. Katkova
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
V. Suslonov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034