Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

M. A. Kinzhalov; M. V. Kashina; A. S. Mikherdov; S. A. Katkova; V. V. Suslonov

doi:10.1134/S107036321806021X

Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

Authors: Kinzhalov M.A.¹, Kashina M.V.¹, Mikherdov A.S.¹, Katkova S.A.¹, Suslonov V.V.¹
Affiliations:
1. St. Petersburg State University
Issue: Vol 88, No 6 (2018)
Pages: 1180-1187
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222252
DOI: https://doi.org/10.1134/S107036321806021X
ID: 222252

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Abstract

Phosphine isocyanide complexes cis-[PtCl₂(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and ¹H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.