Synthesis and Properties of Zinc(II), Cadmium(II), Manganese(III), and Tin(IV) Octakis(4-methoxyphenyl)porphyrins


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详细

Coordination of octakis(4-methoxyphenyl)porphyrin with d-metal salts and metal exchange reactions of its cadmium complex were studied by spectrophotometry in dimethylformamide. Zinc(II), cadmium(II), manganese(III), and tin(IV) octakis(4-methoxyphenyl)porphyrins were isolated and identified. Spectrophotometric titration of zinc(II) octakis(4-methoxyphenyl)porphyrin with 1,4-diazabicyclo[2.2.2]octane afforded the corresponding 1: 1 complex with axial coordination of the extra ligand.

作者简介

N. Chizhova

Krestov Institute of Solution Chemistry

编辑信件的主要联系方式.
Email: nvc@isc-ras.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040

O. Maltceva

Krestov Institute of Solution Chemistry

Email: nvc@isc-ras.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040

S. Zvezdina

Krestov Institute of Solution Chemistry

Email: nvc@isc-ras.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040

N. Mamardashvili

Krestov Institute of Solution Chemistry

Email: nvc@isc-ras.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040

O. Koifman

Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology; Research Institute of the Chemistry of Macroheterocyclic Compounds

Email: nvc@isc-ras.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040; Sheremetevskii pr. 7, Ivanovo, 153000; Sheremetevskii pr. 7, Ivanovo, 153000


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