Email this article Synthesis and Properties of Zinc(II), Cadmium(II), Manganese(III), and Tin(IV) Octakis(4-methoxyphenyl)porphyrins
- Authors: Chizhova N.V.1, Maltceva O.V.1, Zvezdina S.V.1, Mamardashvili N.Z.1, Koifman O.I.1,2,3
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Affiliations:
- Krestov Institute of Solution Chemistry
- Ivanovo State University of Chemistry and Technology
- Research Institute of the Chemistry of Macroheterocyclic Compounds
- Issue: Vol 88, No 5 (2018)
- Pages: 978-984
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222197
- DOI: https://doi.org/10.1134/S1070363218050249
- ID: 222197
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Abstract
Coordination of octakis(4-methoxyphenyl)porphyrin with d-metal salts and metal exchange reactions of its cadmium complex were studied by spectrophotometry in dimethylformamide. Zinc(II), cadmium(II), manganese(III), and tin(IV) octakis(4-methoxyphenyl)porphyrins were isolated and identified. Spectrophotometric titration of zinc(II) octakis(4-methoxyphenyl)porphyrin with 1,4-diazabicyclo[2.2.2]octane afforded the corresponding 1: 1 complex with axial coordination of the extra ligand.
About the authors
N. V. Chizhova
Krestov Institute of Solution Chemistry
Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
O. V. Maltceva
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
S. V. Zvezdina
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
N. Zh. Mamardashvili
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
O. I. Koifman
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology; Research Institute of the Chemistry of Macroheterocyclic Compounds
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040; Sheremetevskii pr. 7, Ivanovo, 153000; Sheremetevskii pr. 7, Ivanovo, 153000
