New Acylhydrazones of Indole Series and Their Metal Complexes
- 作者: Vikrishchuk N.1, Popov L.1, Borodkin G.2, Dranikova A.2, Kletskii M.1, Zagrebaev A.1, Burov O.1
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隶属关系:
- Southern Federal University
- Research Institute of Physical and Organic Chemistry of Southern Federal University
- 期: 卷 88, 编号 5 (2018)
- 页面: 962-967
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222193
- DOI: https://doi.org/10.1134/S1070363218050213
- ID: 222193
如何引用文章
详细
By the reaction of 2-chloroindole-3-carbaldehyde with acylhydrazones new acylhydrazones of the indole series have been synthesized, and their structure, the possibility of cyclization to pyrazoloindoles, and complexing properties have been studied. By means of quantum chemical DFT calculations taking into account the solvent effect it was shown that the reaction of 2-chloroindole-3-carbaldehyde and the corresponding acylhydrazine is an exothermic process, irrespective of which final product is formed, indolemethylenehydrazide or pyrazoloindole. Therefore, both possible transformations in the studied reacting system are controlled kinetically and not thermodynamically.
作者简介
N. Vikrishchuk
Southern Federal University
编辑信件的主要联系方式.
Email: natvi2004@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
L. Popov
Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
G. Borodkin
Research Institute of Physical and Organic Chemistry of Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, Rostov-on-Don
A. Dranikova
Research Institute of Physical and Organic Chemistry of Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, Rostov-on-Don
M. Kletskii
Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
A. Zagrebaev
Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
O. Burov
Southern Federal University
Email: natvi2004@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090