Highly Efficiently Synthesis of Disubstituted Pyrrole Derivatives via Rh(III)-Catalyzed Direct C–H Alkylation Under Mild Conditions

L. Wang; Zh. Li; X. Qu; W. M. Peng; Si Q. Hu; F. Wang

doi:10.1134/S1070363218040217

Highly Efficiently Synthesis of Disubstituted Pyrrole Derivatives via Rh(III)-Catalyzed Direct C–H Alkylation Under Mild Conditions

作者: Wang L.¹, Li Z.¹, Qu X.¹, Peng W.¹, Hu S.¹, Wang F.²
隶属关系:
1. Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Chemical and Environmental Engineering
2. College of Chemistry and Materials Science
期: 卷 88, 编号 4 (2018)
页面: 758-766
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222143
DOI: https://doi.org/10.1134/S1070363218040217
ID: 222143

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详细

A mild and highly efficient Rh(III)-catalyzed direct C–H alkylation of pyrroles with diazo compounds has been developed. This green and atom-economic catalytic process enables an efficient access to various densely functionalized pyrrole derivatives in good to excellent yields, and it is potentially applicable to the large-scale synthesis of pyrrole derivatives.