Peculiar Features of the Willgerodt–Kindler Reaction of 1-Adamantylpropan-2-one and Its Derivatives
- 作者: Novakov I.1, Orlinson B.1, Savel’ev E.1, Potaenkova E.1, Vostrikova O.1, Tarakanov D.1, Nakhod M.1
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隶属关系:
- Volgograd State Technical University
- 期: 卷 87, 编号 12 (2017)
- 页面: 2762-2765
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221673
- DOI: https://doi.org/10.1134/S1070363217120027
- ID: 221673
如何引用文章
详细
The Willgerodt–Kindler reaction of 1-(1-adamantyl)propan-2-one and its derivatives was studied by gas chromatography–mass spectrometry. The reaction time was found to be 3–4 times longer than in the case of alkyl aryl ketones due to considerable steric hindrances in the molecules of adamantyl ketones. The use of diglyme as solvent and sodium butyl xanthate as catalyst significantly shortened the reaction time and improved the yield to 92%.
作者简介
I. Novakov
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
B. Orlinson
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
E. Savel’ev
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
E. Potaenkova
Volgograd State Technical University
编辑信件的主要联系方式.
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
O. Vostrikova
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
D. Tarakanov
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005
M. Nakhod
Volgograd State Technical University
Email: potaoynkova@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400005