Peculiar Features of the Willgerodt–Kindler Reaction of 1-Adamantylpropan-2-one and Its Derivatives
- Autores: Novakov I.1, Orlinson B.1, Savel’ev E.1, Potaenkova E.1, Vostrikova O.1, Tarakanov D.1, Nakhod M.1
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Afiliações:
- Volgograd State Technical University
- Edição: Volume 87, Nº 12 (2017)
- Páginas: 2762-2765
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221673
- DOI: https://doi.org/10.1134/S1070363217120027
- ID: 221673
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Resumo
The Willgerodt–Kindler reaction of 1-(1-adamantyl)propan-2-one and its derivatives was studied by gas chromatography–mass spectrometry. The reaction time was found to be 3–4 times longer than in the case of alkyl aryl ketones due to considerable steric hindrances in the molecules of adamantyl ketones. The use of diglyme as solvent and sodium butyl xanthate as catalyst significantly shortened the reaction time and improved the yield to 92%.
Sobre autores
I. Novakov
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
B. Orlinson
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
E. Savel’ev
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
E. Potaenkova
Volgograd State Technical University
Autor responsável pela correspondência
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
O. Vostrikova
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
D. Tarakanov
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005
M. Nakhod
Volgograd State Technical University
Email: potaoynkova@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400005