Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate. Micelle-forming and adsorption properties
- 作者: Zhil’tsova E.1, Ibatullina M.1, Lukashenko S.1, Kutyreva M.2, Anuar M.1, Kovalenko V.1, Zakharova L.1
-
隶属关系:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Butlerov Institute of Chemistry
- 期: 卷 87, 编号 11 (2017)
- 页面: 2620-2626
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221592
- DOI: https://doi.org/10.1134/S1070363217110172
- ID: 221592
如何引用文章
详细
Novel organometallic surfactants were synthesized from monoquaternized 1,4-diazabicyclo[2.2.2]-octanes of varied hydrophobicity [Alk = CnH2n+1, n = 14, 18] and lanthanum nitrates. The spectral, micelleforming, and adsorption properties of the synthesized compounds were studied by IR, 1Н NMR and electronic spectroscopy, tensiometry, conductometry, and potentiometry. The critical micelle concentrations, counterionic micellar binding constants, and adsorption parameters at the water–air interface were determined and compared with the respective characteristics of the ligands and conventional amphiphiles.
作者简介
E. Zhil’tsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
编辑信件的主要联系方式.
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Kutyreva
Butlerov Institute of Chemistry
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, Tatarstan
M. Anuar
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. Kovalenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088