Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate. Micelle-forming and adsorption properties
- Авторлар: Zhil’tsova E.1, Ibatullina M.1, Lukashenko S.1, Kutyreva M.2, Anuar M.1, Kovalenko V.1, Zakharova L.1
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Мекемелер:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Butlerov Institute of Chemistry
- Шығарылым: Том 87, № 11 (2017)
- Беттер: 2620-2626
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221592
- DOI: https://doi.org/10.1134/S1070363217110172
- ID: 221592
Дәйексөз келтіру
Аннотация
Novel organometallic surfactants were synthesized from monoquaternized 1,4-diazabicyclo[2.2.2]-octanes of varied hydrophobicity [Alk = CnH2n+1, n = 14, 18] and lanthanum nitrates. The spectral, micelleforming, and adsorption properties of the synthesized compounds were studied by IR, 1Н NMR and electronic spectroscopy, tensiometry, conductometry, and potentiometry. The critical micelle concentrations, counterionic micellar binding constants, and adsorption parameters at the water–air interface were determined and compared with the respective characteristics of the ligands and conventional amphiphiles.
Негізгі сөздер
Авторлар туралы
E. Zhil’tsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Хат алмасуға жауапты Автор.
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Kutyreva
Butlerov Institute of Chemistry
Email: Zhiltsova@iopc.ru
Ресей, Kazan, Tatarstan
M. Anuar
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. Kovalenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Ресей, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088