Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate. Micelle-forming and adsorption properties
- Авторы: Zhil’tsova E.1, Ibatullina M.1, Lukashenko S.1, Kutyreva M.2, Anuar M.1, Kovalenko V.1, Zakharova L.1
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Учреждения:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Butlerov Institute of Chemistry
- Выпуск: Том 87, № 11 (2017)
- Страницы: 2620-2626
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221592
- DOI: https://doi.org/10.1134/S1070363217110172
- ID: 221592
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Аннотация
Novel organometallic surfactants were synthesized from monoquaternized 1,4-diazabicyclo[2.2.2]-octanes of varied hydrophobicity [Alk = CnH2n+1, n = 14, 18] and lanthanum nitrates. The spectral, micelleforming, and adsorption properties of the synthesized compounds were studied by IR, 1Н NMR and electronic spectroscopy, tensiometry, conductometry, and potentiometry. The critical micelle concentrations, counterionic micellar binding constants, and adsorption parameters at the water–air interface were determined and compared with the respective characteristics of the ligands and conventional amphiphiles.
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E. Zhil’tsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Автор, ответственный за переписку.
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. Kutyreva
Butlerov Institute of Chemistry
Email: Zhiltsova@iopc.ru
Россия, Kazan, Tatarstan
M. Anuar
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. Kovalenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: Zhiltsova@iopc.ru
Россия, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088