Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)
- 作者: Chernysheva A.1, Shelyganov P.1, Kazakov I.1, Timoshkin A.1
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隶属关系:
- St. Petersburg State University
- 期: 卷 87, 编号 4 (2017)
- 页面: 665-669
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219136
- DOI: https://doi.org/10.1134/S1070363217040016
- ID: 219136
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详细
Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.
作者简介
A. Chernysheva
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
P. Shelyganov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
I. Kazakov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Timoshkin
St. Petersburg State University
编辑信件的主要联系方式.
Email: a.y.timoshkin@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034