Отправить статью по E-mail Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)
- Авторы: Chernysheva A.1, Shelyganov P.1, Kazakov I.1, Timoshkin A.1
-
Учреждения:
- St. Petersburg State University
- Выпуск: Том 87, № 4 (2017)
- Страницы: 665-669
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219136
- DOI: https://doi.org/10.1134/S1070363217040016
- ID: 219136
Цитировать
Открытый доступ
Доступ предоставлен
Только для подписчиков
Аннотация
Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.
Ключевые слова
Об авторах
A. Chernysheva
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Россия, Universitetskaya nab. 7–9, St. Petersburg, 199034
P. Shelyganov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Россия, Universitetskaya nab. 7–9, St. Petersburg, 199034
I. Kazakov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Россия, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Timoshkin
St. Petersburg State University
Автор, ответственный за переписку.
Email: a.y.timoshkin@spbu.ru
Россия, Universitetskaya nab. 7–9, St. Petersburg, 199034
