Enviar artigo por via de e-mail Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)
- Autores: Chernysheva A.1, Shelyganov P.1, Kazakov I.1, Timoshkin A.1
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Afiliações:
- St. Petersburg State University
- Edição: Volume 87, Nº 4 (2017)
- Páginas: 665-669
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219136
- DOI: https://doi.org/10.1134/S1070363217040016
- ID: 219136
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Resumo
Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.
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Sobre autores
A. Chernysheva
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
P. Shelyganov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
I. Kazakov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Timoshkin
St. Petersburg State University
Autor responsável pela correspondência
Email: a.y.timoshkin@spbu.ru
Rússia, Universitetskaya nab. 7–9, St. Petersburg, 199034
