Azobenzene palladium(II) complexes with β-diketones
- 作者: Nikolaeva M.1, Bogdanova E.1, Puzyk M.1
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隶属关系:
- Herzen State Pedagogical University of Russia
- 期: 卷 87, 编号 3 (2017)
- 页面: 485-488
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218793
- DOI: https://doi.org/10.1134/S1070363217030185
- ID: 218793
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详细
A procedure has been developed for the synthesis of cyclometalated azobenzene palladium(II) complexes [Pd(O^O)Azb], where Azb– is deprotonated azobenzene and (O^O)– is deprotonated β-diketone (acetylacetone, thenoyltrifluoroacetone, benzoylacetone, or dibenzoylmethane). Electronic absorption spectra and electrochemical behavior of the synthesized complexes have been studied. It has been found that the lowest unoccupied molecular orbital of the complexes is contributed most by the π* orbital of azobenzene, and the highest occupied molecular orbital, by the palladium d orbital.
作者简介
M. Nikolaeva
Herzen State Pedagogical University of Russia
编辑信件的主要联系方式.
Email: nikolaeva.mr@gmail.com
俄罗斯联邦, nab. r. Moiki 48, St. Petersburg, 191186
E. Bogdanova
Herzen State Pedagogical University of Russia
Email: nikolaeva.mr@gmail.com
俄罗斯联邦, nab. r. Moiki 48, St. Petersburg, 191186
M. Puzyk
Herzen State Pedagogical University of Russia
Email: nikolaeva.mr@gmail.com
俄罗斯联邦, nab. r. Moiki 48, St. Petersburg, 191186