Azobenzene palladium(II) complexes with β-diketones
- Авторлар: Nikolaeva M.1, Bogdanova E.1, Puzyk M.1
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Мекемелер:
- Herzen State Pedagogical University of Russia
- Шығарылым: Том 87, № 3 (2017)
- Беттер: 485-488
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218793
- DOI: https://doi.org/10.1134/S1070363217030185
- ID: 218793
Дәйексөз келтіру
Аннотация
A procedure has been developed for the synthesis of cyclometalated azobenzene palladium(II) complexes [Pd(O^O)Azb], where Azb– is deprotonated azobenzene and (O^O)– is deprotonated β-diketone (acetylacetone, thenoyltrifluoroacetone, benzoylacetone, or dibenzoylmethane). Electronic absorption spectra and electrochemical behavior of the synthesized complexes have been studied. It has been found that the lowest unoccupied molecular orbital of the complexes is contributed most by the π* orbital of azobenzene, and the highest occupied molecular orbital, by the palladium d orbital.
Авторлар туралы
M. Nikolaeva
Herzen State Pedagogical University of Russia
Хат алмасуға жауапты Автор.
Email: nikolaeva.mr@gmail.com
Ресей, nab. r. Moiki 48, St. Petersburg, 191186
E. Bogdanova
Herzen State Pedagogical University of Russia
Email: nikolaeva.mr@gmail.com
Ресей, nab. r. Moiki 48, St. Petersburg, 191186
M. Puzyk
Herzen State Pedagogical University of Russia
Email: nikolaeva.mr@gmail.com
Ресей, nab. r. Moiki 48, St. Petersburg, 191186
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