Quantum chemical study of the adducts of azomethine cobalt complexes with acenaphthene-1,2-diimines
- 作者: Starikov A.1,2, Starikova A.2, Minkin V.1,2
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隶属关系:
- Southern Scientific Center of Russian Academy of Sciences
- Institute of Physical and Organic Chemistry
- 期: 卷 87, 编号 1 (2017)
- 页面: 98-106
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217929
- DOI: https://doi.org/10.1134/S1070363217010169
- ID: 217929
如何引用文章
详细
Adducts based on the cobalt azomethine bis-chelates and acenaphthene-1,2-diimines have been studied using the density functional theory method [DFT B3LYP*/6-311++G(d,p)]. It has been shown that the stability of the formed complexes with respect to dissociation and the ability to demonstrate valence tautomeric properties can be controlled by functionalization of the ligands. Compounds have been revealed whose magnetic properties vary due to intramolecular redox process.
作者简介
A. Starikov
Southern Scientific Center of Russian Academy of Sciences; Institute of Physical and Organic Chemistry
编辑信件的主要联系方式.
Email: andr@ipoc.sfedu.ru
俄罗斯联邦, ul. Chekhova 41, Rostov-on-Don, 344006; Rostov-on-Don
A. Starikova
Institute of Physical and Organic Chemistry
Email: andr@ipoc.sfedu.ru
俄罗斯联邦, Rostov-on-Don
V. Minkin
Southern Scientific Center of Russian Academy of Sciences; Institute of Physical and Organic Chemistry
Email: andr@ipoc.sfedu.ru
俄罗斯联邦, ul. Chekhova 41, Rostov-on-Don, 344006; Rostov-on-Don
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