Email this article Quantum chemical study of the adducts of azomethine cobalt complexes with acenaphthene-1,2-diimines
- Authors: Starikov A.G.1,2, Starikova A.A.2, Minkin V.I.1,2
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Affiliations:
- Southern Scientific Center of Russian Academy of Sciences
- Institute of Physical and Organic Chemistry
- Issue: Vol 87, No 1 (2017)
- Pages: 98-106
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217929
- DOI: https://doi.org/10.1134/S1070363217010169
- ID: 217929
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Abstract
Adducts based on the cobalt azomethine bis-chelates and acenaphthene-1,2-diimines have been studied using the density functional theory method [DFT B3LYP*/6-311++G(d,p)]. It has been shown that the stability of the formed complexes with respect to dissociation and the ability to demonstrate valence tautomeric properties can be controlled by functionalization of the ligands. Compounds have been revealed whose magnetic properties vary due to intramolecular redox process.
About the authors
A. G. Starikov
Southern Scientific Center of Russian Academy of Sciences; Institute of Physical and Organic Chemistry
Author for correspondence.
Email: andr@ipoc.sfedu.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006; Rostov-on-Don
A. A. Starikova
Institute of Physical and Organic Chemistry
Email: andr@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don
V. I. Minkin
Southern Scientific Center of Russian Academy of Sciences; Institute of Physical and Organic Chemistry
Email: andr@ipoc.sfedu.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006; Rostov-on-Don
