Effect of poly(ethylene oxide) on the kinetics of oxidative polymerization of aniline
- 作者: Mezhuev Y.1, Korshak Y.1, Shtil’man M.1
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隶属关系:
- Mendeleev University of Chemical Technology of Russia
- 期: 卷 86, 编号 11 (2016)
- 页面: 2520-2525
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216572
- DOI: https://doi.org/10.1134/S1070363216110190
- ID: 216572
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详细
The kinetics of polymerization of aniline hydrochloride in aqueous poly(ethylene oxide) solution in the presence of ammonium persulfate have been studied. The order of the catalytic step has been found to change from first to second when the molecular weight of poly(ethylene oxide) reaches a certain value. Adsorption equilibrium is rapidly established between the monomer and its oxidation products which give rise to a new phase and exert a catalytic effect.
作者简介
Ya. Mezhuev
Mendeleev University of Chemical Technology of Russia
编辑信件的主要联系方式.
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
Yu. Korshak
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
M. Shtil’man
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047