Email this article Effect of poly(ethylene oxide) on the kinetics of oxidative polymerization of aniline
- Authors: Mezhuev Y.O.1, Korshak Y.V.1, Shtil’man M.I.1
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Affiliations:
- Mendeleev University of Chemical Technology of Russia
- Issue: Vol 86, No 11 (2016)
- Pages: 2520-2525
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216572
- DOI: https://doi.org/10.1134/S1070363216110190
- ID: 216572
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Abstract
The kinetics of polymerization of aniline hydrochloride in aqueous poly(ethylene oxide) solution in the presence of ammonium persulfate have been studied. The order of the catalytic step has been found to change from first to second when the molecular weight of poly(ethylene oxide) reaches a certain value. Adsorption equilibrium is rapidly established between the monomer and its oxidation products which give rise to a new phase and exert a catalytic effect.
About the authors
Ya. O. Mezhuev
Mendeleev University of Chemical Technology of Russia
Author for correspondence.
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
Yu. V. Korshak
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
M. I. Shtil’man
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
