Chalcogenation of 1,3-dichloropropene with elemental chalcogens in the system hydrazine hydrate–base
- 作者: Levanova E.1, Nikonova V.1, Grabel’nykh V.1, Rozentsveig I.1, Russavskaya N.1, Albanov A.1, Korchevin N.1
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隶属关系:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- 期: 卷 86, 编号 6 (2016)
- 页面: 1282-1287
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215239
- DOI: https://doi.org/10.1134/S1070363216060104
- ID: 215239
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详细
Sulfur reacts with 1,3-dichloropropene in the system hydrazine hydrate–KOH to form bis(1-chloroprop-1-en-3-yl) sulfide, and in the system hydrazine hydrate–monoethanolamine, bis(1-chloroprop-1-en- 3-yl) disulfide. The reaction of tellurium in the system hydrazine hydrate–KOH leads to diallyl telluride, the product of nucleophilic substitution of the allylic chlorine atom and reductive cleavage of the Сsp2–Cl bond. The reaction of selenium with 1,3-dichloropropene gives a complex mixture of products. At excess KOH (Se: KOH = 1: 5) bis(1-chloroprop-1-en-3-yl) selenide was isolated.
作者简介
E. Levanova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
编辑信件的主要联系方式.
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
V. Nikonova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
V. Grabel’nykh
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
I. Rozentsveig
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
N. Russavskaya
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
N. Korchevin
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033