Chalcogenation of 1,3-dichloropropene with elemental chalcogens in the system hydrazine hydrate–base
- Авторы: Levanova E.1, Nikonova V.1, Grabel’nykh V.1, Rozentsveig I.1, Russavskaya N.1, Albanov A.1, Korchevin N.1
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Учреждения:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Выпуск: Том 86, № 6 (2016)
- Страницы: 1282-1287
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215239
- DOI: https://doi.org/10.1134/S1070363216060104
- ID: 215239
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Аннотация
Sulfur reacts with 1,3-dichloropropene in the system hydrazine hydrate–KOH to form bis(1-chloroprop-1-en-3-yl) sulfide, and in the system hydrazine hydrate–monoethanolamine, bis(1-chloroprop-1-en- 3-yl) disulfide. The reaction of tellurium in the system hydrazine hydrate–KOH leads to diallyl telluride, the product of nucleophilic substitution of the allylic chlorine atom and reductive cleavage of the Сsp2–Cl bond. The reaction of selenium with 1,3-dichloropropene gives a complex mixture of products. At excess KOH (Se: KOH = 1: 5) bis(1-chloroprop-1-en-3-yl) selenide was isolated.
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Об авторах
E. Levanova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Автор, ответственный за переписку.
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
V. Nikonova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
V. Grabel’nykh
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
I. Rozentsveig
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
N. Russavskaya
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
N. Korchevin
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033