Chalcogenation of 1,3-dichloropropene with elemental chalcogens in the system hydrazine hydrate–base
- Autores: Levanova E.1, Nikonova V.1, Grabel’nykh V.1, Rozentsveig I.1, Russavskaya N.1, Albanov A.1, Korchevin N.1
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Afiliações:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Edição: Volume 86, Nº 6 (2016)
- Páginas: 1282-1287
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215239
- DOI: https://doi.org/10.1134/S1070363216060104
- ID: 215239
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Resumo
Sulfur reacts with 1,3-dichloropropene in the system hydrazine hydrate–KOH to form bis(1-chloroprop-1-en-3-yl) sulfide, and in the system hydrazine hydrate–monoethanolamine, bis(1-chloroprop-1-en- 3-yl) disulfide. The reaction of tellurium in the system hydrazine hydrate–KOH leads to diallyl telluride, the product of nucleophilic substitution of the allylic chlorine atom and reductive cleavage of the Сsp2–Cl bond. The reaction of selenium with 1,3-dichloropropene gives a complex mixture of products. At excess KOH (Se: KOH = 1: 5) bis(1-chloroprop-1-en-3-yl) selenide was isolated.
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Sobre autores
E. Levanova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Autor responsável pela correspondência
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
V. Nikonova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
V. Grabel’nykh
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
I. Rozentsveig
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
N. Russavskaya
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
N. Korchevin
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: venk@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
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