New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization
- Авторы: Samokhvalova S.1, Ershov V.1, Lukyanov D.1, Vlasov P.1, Levin O.1
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Учреждения:
- St. Petersburg State University
- Выпуск: Том 89, № 4 (2019)
- Страницы: 852-855
- Раздел: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222888
- DOI: https://doi.org/10.1134/S1070363219040352
- ID: 222888
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Аннотация
New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.
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Об авторах
S. Samokhvalova
St. Petersburg State University
Email: o.levin@spbu.ru
Россия, Universitetskii pr. 26, St. Petersburg, 198504
V. Ershov
St. Petersburg State University
Email: o.levin@spbu.ru
Россия, Universitetskii pr. 26, St. Petersburg, 198504
D. Lukyanov
St. Petersburg State University
Email: o.levin@spbu.ru
Россия, Universitetskii pr. 26, St. Petersburg, 198504
P. Vlasov
St. Petersburg State University
Email: o.levin@spbu.ru
Россия, Universitetskii pr. 26, St. Petersburg, 198504
O. Levin
St. Petersburg State University
Автор, ответственный за переписку.
Email: o.levin@spbu.ru
Россия, Universitetskii pr. 26, St. Petersburg, 198504
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