New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization
- 作者: Samokhvalova S.1, Ershov V.1, Lukyanov D.1, Vlasov P.1, Levin O.1
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隶属关系:
- St. Petersburg State University
- 期: 卷 89, 编号 4 (2019)
- 页面: 852-855
- 栏目: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222888
- DOI: https://doi.org/10.1134/S1070363219040352
- ID: 222888
如何引用文章
详细
New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.
作者简介
S. Samokhvalova
St. Petersburg State University
Email: o.levin@spbu.ru
俄罗斯联邦, Universitetskii pr. 26, St. Petersburg, 198504
V. Ershov
St. Petersburg State University
Email: o.levin@spbu.ru
俄罗斯联邦, Universitetskii pr. 26, St. Petersburg, 198504
D. Lukyanov
St. Petersburg State University
Email: o.levin@spbu.ru
俄罗斯联邦, Universitetskii pr. 26, St. Petersburg, 198504
P. Vlasov
St. Petersburg State University
Email: o.levin@spbu.ru
俄罗斯联邦, Universitetskii pr. 26, St. Petersburg, 198504
O. Levin
St. Petersburg State University
编辑信件的主要联系方式.
Email: o.levin@spbu.ru
俄罗斯联邦, Universitetskii pr. 26, St. Petersburg, 198504
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