Comparative Study of Redox Reactions of Aqua- and Thiocyanatocobalamin
- Авторы: Salnikov D.1, Makarov S.1, Ivlev P.1
-
Учреждения:
- Ivanovo State University of Chemistry and Technology
- Выпуск: Том 88, № 5 (2018)
- Страницы: 958-961
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222191
- DOI: https://doi.org/10.1134/S1070363218050201
- ID: 222191
Цитировать
Аннотация
The interaction of aqua- and thiocyanatocobalamin with sodium hydroxymethanesulfinate in neutral aqueous solution has been studied, and the kinetic as well as activation parameters of the reactions have been determined. The reduction of the aqua complex is faster in comparison with the thiocyanato one. In contrast to the earlier studied reaction of hydroxymethanesulfinate with cyanocobalamin, reduction of aquaand thiocycnatocobalamins occurs via the associative mechanism.
Ключевые слова
Об авторах
D. Salnikov
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: densal@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
S. Makarov
Ivanovo State University of Chemistry and Technology
Email: densal@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
P. Ivlev
Ivanovo State University of Chemistry and Technology
Email: densal@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
![](/img/style/loading.gif)