Enviar artigo por via de e-mail Elementary Stages of Photochemical Reactions of Substituted 2,6-Diphenyl-para-benzoquinones with Thiols
- Autores: Porkhun V.1, Porkhun E.1, Gurulev D.1, Palatkina L.1
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Afiliações:
- Volgograd State Technical University
- Edição: Volume 88, Nº 8 (2018)
- Páginas: 1580-1583
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222350
- DOI: https://doi.org/10.1134/S1070363218080042
- ID: 222350
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Resumo
Using the effects of chemical polarization of nuclei, mechanism and elementary stages of photochemical reduction of 2,6-diphenyl-1,4-benzoquinone with thiols have been elucidated. The studied quinone is reduced with ethanethiol in two stages (transfer of electron followed by proton transfer). The final photolysis product is a derivative of dibenzofuran.
Sobre autores
V. Porkhun
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Rússia, pr. Lenina 28, Volgograd, 400005
E. Porkhun
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Rússia, pr. Lenina 28, Volgograd, 400005
D. Gurulev
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Rússia, pr. Lenina 28, Volgograd, 400005
L. Palatkina
Volgograd State Technical University
Autor responsável pela correspondência
Email: lv.palatkina@yandex.ru
Rússia, pr. Lenina 28, Volgograd, 400005
