Email this article Elementary Stages of Photochemical Reactions of Substituted 2,6-Diphenyl-para-benzoquinones with Thiols
- Authors: Porkhun V.I.1, Porkhun E.V.1, Gurulev D.N.1, Palatkina L.V.1
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Affiliations:
- Volgograd State Technical University
- Issue: Vol 88, No 8 (2018)
- Pages: 1580-1583
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222350
- DOI: https://doi.org/10.1134/S1070363218080042
- ID: 222350
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Abstract
Using the effects of chemical polarization of nuclei, mechanism and elementary stages of photochemical reduction of 2,6-diphenyl-1,4-benzoquinone with thiols have been elucidated. The studied quinone is reduced with ethanethiol in two stages (transfer of electron followed by proton transfer). The final photolysis product is a derivative of dibenzofuran.
About the authors
V. I. Porkhun
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Russian Federation, pr. Lenina 28, Volgograd, 400005
E. V. Porkhun
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Russian Federation, pr. Lenina 28, Volgograd, 400005
D. N. Gurulev
Volgograd State Technical University
Email: lv.palatkina@yandex.ru
Russian Federation, pr. Lenina 28, Volgograd, 400005
L. V. Palatkina
Volgograd State Technical University
Author for correspondence.
Email: lv.palatkina@yandex.ru
Russian Federation, pr. Lenina 28, Volgograd, 400005
