Enviar artigo por via de e-mail Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite
- Autores: Tatarinov D.1,2, Kundina M.2, Dobrynin A.1, Mironov V.1,2
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Afiliações:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Kazan (Volga Region) Federal University
- Edição: Volume 88, Nº 1 (2018)
- Páginas: 90-95
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221951
- DOI: https://doi.org/10.1134/S1070363218010140
- ID: 221951
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Resumo
Bis(trimethylsilyl) hypophosphite reacts with unsaturated ketones (methyl vinyl ketone and mesityl oxide) to give, depending on the reaction conditions, 1: 1 or 1: 2 adducts after hydrolysis. It was found that the intramolecular cyclization of the 1: 2 reaction product with mesityl oxide, trimethylsilyl bis(2-methyl-4- oxopentan-2-yl)phosphinate, yields, after hydrolysis, a phosphorinane with exocyclic carbonyl and hydroxyl groups.
Sobre autores
D. Tatarinov
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center; Kazan (Volga Region) Federal University
Autor responsável pela correspondência
Email: datint@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
M. Kundina
Kazan (Volga Region) Federal University
Email: datint@iopc.ru
Rússia, Kazan, Tatarstan
A. Dobrynin
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: datint@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. Mironov
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center; Kazan (Volga Region) Federal University
Email: datint@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
