Email this article Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite
- Authors: Tatarinov D.A.1,2, Kundina M.V.2, Dobrynin A.B.1, Mironov V.F.1,2
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Affiliations:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Kazan (Volga Region) Federal University
- Issue: Vol 88, No 1 (2018)
- Pages: 90-95
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221951
- DOI: https://doi.org/10.1134/S1070363218010140
- ID: 221951
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Abstract
Bis(trimethylsilyl) hypophosphite reacts with unsaturated ketones (methyl vinyl ketone and mesityl oxide) to give, depending on the reaction conditions, 1: 1 or 1: 2 adducts after hydrolysis. It was found that the intramolecular cyclization of the 1: 2 reaction product with mesityl oxide, trimethylsilyl bis(2-methyl-4- oxopentan-2-yl)phosphinate, yields, after hydrolysis, a phosphorinane with exocyclic carbonyl and hydroxyl groups.
About the authors
D. A. Tatarinov
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center; Kazan (Volga Region) Federal University
Author for correspondence.
Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
M. V. Kundina
Kazan (Volga Region) Federal University
Email: datint@iopc.ru
Russian Federation, Kazan, Tatarstan
A. B. Dobrynin
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. F. Mironov
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center; Kazan (Volga Region) Federal University
Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
