Unusual Reaction of 6,8-Dichloro-3,3-dimethyl-7-nitro-3 H -2,1,4-benzoxadiazine 4-Oxide with 4-Aminomorpholine

E. A. Chugunova; N. I. Akylbekov; M. R. Gaziev; V. A. Samsonov; A. B. Dobrynin; A. R. Burilov

doi:10.1134/S1070363217120222

Unusual Reaction of 6,8-Dichloro-3,3-dimethyl-7-nitro-3H-2,1,4-benzoxadiazine 4-Oxide with 4-Aminomorpholine

Autores: Chugunova E.¹^,2, Akylbekov N.³, Gaziev M.³, Samsonov V.⁴, Dobrynin A.³, Burilov A.¹
Afiliações:
1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
2. Kazan Federal University
3. Kazan National Research Technological University
4. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Edição: Volume 87, Nº 12 (2017)
Páginas: 2884-2886
Seção: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/221723
DOI: https://doi.org/10.1134/S1070363217120222
ID: 221723

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Resumo

Reaction of 6,8-dichloro-3,3-dimethyl-7-nitro-3H-2,1,4-benzoxadiazine 4-oxide with 4-aminomorpholine occurred through the benzoxadiazine ring opening to form 1,2-bis(2-amino-3,5-dichloro-4-nitrophenyl)-diazene oxide instead of the substitution product.

Palavras-chave

3H-2,1,4-benzoxadiazine 4-oxide, 4-aminomorpholine, heterocyclic compounds

Sobre autores

E. Chugunova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University

Autor responsável pela correspondência
Email: elena-chugunova@list.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan