Unusual Reaction of 6,8-Dichloro-3,3-dimethyl-7-nitro-3 H -2,1,4-benzoxadiazine 4-Oxide with 4-Aminomorpholine

E. A. Chugunova; N. I. Akylbekov; M. R. Gaziev; V. A. Samsonov; A. B. Dobrynin; A. R. Burilov

doi:10.1134/S1070363217120222

Unusual Reaction of 6,8-Dichloro-3,3-dimethyl-7-nitro-3H-2,1,4-benzoxadiazine 4-Oxide with 4-Aminomorpholine

Authors: Chugunova E.A.¹^,2, Akylbekov N.I.³, Gaziev M.R.³, Samsonov V.A.⁴, Dobrynin A.B.³, Burilov A.R.¹
Affiliations:
1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
2. Kazan Federal University
3. Kazan National Research Technological University
4. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Issue: Vol 87, No 12 (2017)
Pages: 2884-2886
Section: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/221723
DOI: https://doi.org/10.1134/S1070363217120222
ID: 221723

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Abstract
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Abstract

Reaction of 6,8-dichloro-3,3-dimethyl-7-nitro-3H-2,1,4-benzoxadiazine 4-oxide with 4-aminomorpholine occurred through the benzoxadiazine ring opening to form 1,2-bis(2-amino-3,5-dichloro-4-nitrophenyl)-diazene oxide instead of the substitution product.

Keywords

3H-2,1,4-benzoxadiazine 4-oxide, 4-aminomorpholine, heterocyclic compounds

About the authors

E. A. Chugunova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University

Author for correspondence.
Email: elena-chugunova@list.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan