Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane

Resumo

A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph₂P(O)CH₂O(CH₂CH₂O)_nCH₂P(O)Ph₂ (Lⁿ, n = 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis.