Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane
- Authors: Ivanova I.S.1,2, Baulin V.E.2,3, Polyakova I.N.1, Pyatova E.N.1,2, Krivorot’ko E.S.2, Galkina E.N.1, Tsivadze A.Y.2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Physiologically Active Substances
- Issue: Vol 87, No 11 (2017)
- Pages: 2574-2581
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221565
- DOI: https://doi.org/10.1134/S107036321711010X
- ID: 221565
Cite item
Abstract
A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (Ln, n = 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis.
About the authors
I. S. Ivanova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: isivanova@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Moscow
V. E. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Physiologically Active Substances
Email: isivanova@mail.ru
Russian Federation, Moscow; Chernogolovka, Moscow oblast
I. N. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
E. N. Pyatova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Moscow
E. S. Krivorot’ko
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Moscow
E. N. Galkina
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Moscow
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