Reaction of 1,4-benzoquinones with PH-phosphonium salts


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Resumo

A novel approach has been proposed to the synthesis of phosphonium salts containing a 1,4-dihydroxybenzo fragment via reaction of 2-methyl-1,4-benzoquinone or 2-isopropyl-5-methyl-1,4-benzoquinone with PH-phosphonium salts generated in situ from triphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acid. The structure of the synthesized phosphonium salts was determined by NMR spectroscopy and X-ray analysis.

Sobre autores

N. Khasiyatullina

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Autor responsável pela correspondência
Email: nadya.ksu@mail.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

A. Vazykhova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: nadya.ksu@mail.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

Yu. Voronina

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: nadya.ksu@mail.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

V. Mironov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: nadya.ksu@mail.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2017

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