Email this article Reaction of 1,4-benzoquinones with PH-phosphonium salts
- Authors: Khasiyatullina N.R.1, Vazykhova A.M.1, Voronina Y.K.1, Mironov V.F.1
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Issue: Vol 87, No 9 (2017)
- Pages: 1934-1940
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221201
- DOI: https://doi.org/10.1134/S1070363217090079
- ID: 221201
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Abstract
A novel approach has been proposed to the synthesis of phosphonium salts containing a 1,4-dihydroxybenzo fragment via reaction of 2-methyl-1,4-benzoquinone or 2-isopropyl-5-methyl-1,4-benzoquinone with PH-phosphonium salts generated in situ from triphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acid. The structure of the synthesized phosphonium salts was determined by NMR spectroscopy and X-ray analysis.
About the authors
N. R. Khasiyatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Author for correspondence.
Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
A. M. Vazykhova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
Yu. K. Voronina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. F. Mironov
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
