Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes


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Resumo

The complex formation of zinc(II) acetate with monoiodo- and dibromo-substituted dipyrromethenes in DMF at 298.15 K were studied by means of spectrophotometric titration. It was found that the process involves consecutive formation of heteroligand [ZnLOAc] and homoligand [ZnL2] complexes. The thermodynamic stability of halogenated zinc(II) dipyrrolylmethenates [ZnL2] was studied.

Sobre autores

E. Nuraneeva

G.A. Krestov Institution of Solution Chemistry

Email: gbg@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045

G. Guseva

G.A. Krestov Institution of Solution Chemistry

Autor responsável pela correspondência
Email: gbg@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045

E. Antina

G.A. Krestov Institution of Solution Chemistry

Email: gbg@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2017

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