Email this article Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes
- Authors: Nuraneeva E.N.1, Guseva G.B.1, Antina E.V.1
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Affiliations:
- G.A. Krestov Institution of Solution Chemistry
- Issue: Vol 87, No 7 (2017)
- Pages: 1550-1556
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220741
- DOI: https://doi.org/10.1134/S1070363217070180
- ID: 220741
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Abstract
The complex formation of zinc(II) acetate with monoiodo- and dibromo-substituted dipyrromethenes in DMF at 298.15 K were studied by means of spectrophotometric titration. It was found that the process involves consecutive formation of heteroligand [ZnLOAc] and homoligand [ZnL2] complexes. The thermodynamic stability of halogenated zinc(II) dipyrrolylmethenates [ZnL2] was studied.
About the authors
E. N. Nuraneeva
G.A. Krestov Institution of Solution Chemistry
Email: gbg@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
G. B. Guseva
G.A. Krestov Institution of Solution Chemistry
Author for correspondence.
Email: gbg@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
E. V. Antina
G.A. Krestov Institution of Solution Chemistry
Email: gbg@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
