Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene

V. P. Sheverdov; M. A. Mar’yasov; V. V. Davydova; O. E. Nasakin; P. V. Dorovatovskii; V. N. Khrustalev

doi:10.1134/S1070363217070088

Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene

Autores: Sheverdov V.¹, Mar’yasov M.¹, Davydova V.¹, Nasakin O.¹, Dorovatovskii P.², Khrustalev V.³^,4
Afiliações:
1. Ul’yanov Chuvash State University
2. National Research Center “Kurchatov Institute,”
3. Russian People’s Friendship University
4. Nesmeyanov Institute of Organoelemental Compounds
Edição: Volume 87, Nº 7 (2017)
Páginas: 1490-1494
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/220644
DOI: https://doi.org/10.1134/S1070363217070088
ID: 220644

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Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene yielded methyl 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylates. X-Ray diffraction data showed that 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylic acid methyl esters can form supramolecular structures with one-dimensional channels which make possible inclusion of large organic and bioorganic molecules.