Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene


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Abstract

Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene yielded methyl 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylates. X-Ray diffraction data showed that 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylic acid methyl esters can form supramolecular structures with one-dimensional channels which make possible inclusion of large organic and bioorganic molecules.

About the authors

V. P. Sheverdov

Ul’yanov Chuvash State University

Author for correspondence.
Email: SheverdovVP@yandex.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015

M. A. Mar’yasov

Ul’yanov Chuvash State University

Email: SheverdovVP@yandex.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015

V. V. Davydova

Ul’yanov Chuvash State University

Email: SheverdovVP@yandex.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015

O. E. Nasakin

Ul’yanov Chuvash State University

Email: SheverdovVP@yandex.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015

P. V. Dorovatovskii

National Research Center “Kurchatov Institute,”

Email: SheverdovVP@yandex.ru
Russian Federation, Moscow

V. N. Khrustalev

Russian People’s Friendship University; Nesmeyanov Institute of Organoelemental Compounds

Email: SheverdovVP@yandex.ru
Russian Federation, Moscow; Moscow


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