Enviar artigo por via de e-mail Reaction of [Pt(NH3)4]Cl2·H2O with (NH4)6Mo7O24·4H2O in an aqueous alkaline solution at 190°C (autoclaving conditions)
- Autores: Fesik E.1,2, Buslayeva T.3, Mel’nikova T.4
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Afiliações:
- Samara University
- Medical University “Reaviz”
- Moscow State Technological University (Institute of Fine Chemical Technologies)
- Nonprofit Partnership “Assistance to Chemical and Environmental Education”
- Edição: Volume 87, Nº 2 (2017)
- Páginas: 159-162
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218096
- DOI: https://doi.org/10.1134/S1070363217020013
- ID: 218096
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Resumo
A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed.
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Sobre autores
E. Fesik
Samara University; Medical University “Reaviz”
Autor responsável pela correspondência
Email: 1707-fesik@mail.ru
Rússia, Moskovskoe sh. 34, Samara, 443086; Samara
T. Buslayeva
Moscow State Technological University (Institute of Fine Chemical Technologies)
Email: 1707-fesik@mail.ru
Rússia, Moscow
T. Mel’nikova
Nonprofit Partnership “Assistance to Chemical and Environmental Education”
Email: 1707-fesik@mail.ru
Rússia, Moscow
