Email this article Reaction of [Pt(NH3)4]Cl2·H2O with (NH4)6Mo7O24·4H2O in an aqueous alkaline solution at 190°C (autoclaving conditions)
- Authors: Fesik E.V.1,2, Buslayeva T.M.3, Mel’nikova T.I.4
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Affiliations:
- Samara University
- Medical University “Reaviz”
- Moscow State Technological University (Institute of Fine Chemical Technologies)
- Nonprofit Partnership “Assistance to Chemical and Environmental Education”
- Issue: Vol 87, No 2 (2017)
- Pages: 159-162
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218096
- DOI: https://doi.org/10.1134/S1070363217020013
- ID: 218096
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Abstract
A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed.
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About the authors
E. V. Fesik
Samara University; Medical University “Reaviz”
Author for correspondence.
Email: 1707-fesik@mail.ru
Russian Federation, Moskovskoe sh. 34, Samara, 443086; Samara
T. M. Buslayeva
Moscow State Technological University (Institute of Fine Chemical Technologies)
Email: 1707-fesik@mail.ru
Russian Federation, Moscow
T. I. Mel’nikova
Nonprofit Partnership “Assistance to Chemical and Environmental Education”
Email: 1707-fesik@mail.ru
Russian Federation, Moscow
