Phenomenon of isoparametricity in reactions of trans-2,3-diaryloxiranes with arenesulfonic acids. Mechanistic interpretation
- Autores: Shpan’ko I.1, Sadovaya I.1
-
Afiliações:
- Donetsk National University
- Edição: Volume 86, Nº 11 (2016)
- Páginas: 2418-2422
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216473
- DOI: https://doi.org/10.1134/S1070363216110037
- ID: 216473
Citar
Resumo
Nonadditive effects of substituents X and Y are manifested in reactions of symmetrically X-substituted trans-2,3-diaryloxiranes with Y-substituted arenesulfonic acids. The isoparametric point is reached experimentally: close to the point τXIP = 4.73 on substituent Х the rate of the oxirane ring opening of trans-2,3-bis(3-bromo-5-nitrophenyl)oxirane (τX = 4.38) practically does not depend on substituent Y (ρYX = 0.10±0.05). The results of cross correlation analysis of the kinetic data are applied to interpretation of the mechanism of the studied reactions.
Sobre autores
I. Shpan’ko
Donetsk National University
Autor responsável pela correspondência
Email: shpanko09@rambler.ru
Ucrânia, ul. 600-letiya 21, Vinnitsa, 21021
I. Sadovaya
Donetsk National University
Email: shpanko09@rambler.ru
Ucrânia, ul. 600-letiya 21, Vinnitsa, 21021