Phenomenon of isoparametricity in reactions of trans-2,3-diaryloxiranes with arenesulfonic acids. Mechanistic interpretation
- Авторлар: Shpan’ko I.1, Sadovaya I.1
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Мекемелер:
- Donetsk National University
- Шығарылым: Том 86, № 11 (2016)
- Беттер: 2418-2422
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216473
- DOI: https://doi.org/10.1134/S1070363216110037
- ID: 216473
Дәйексөз келтіру
Аннотация
Nonadditive effects of substituents X and Y are manifested in reactions of symmetrically X-substituted trans-2,3-diaryloxiranes with Y-substituted arenesulfonic acids. The isoparametric point is reached experimentally: close to the point τXIP = 4.73 on substituent Х the rate of the oxirane ring opening of trans-2,3-bis(3-bromo-5-nitrophenyl)oxirane (τX = 4.38) practically does not depend on substituent Y (ρYX = 0.10±0.05). The results of cross correlation analysis of the kinetic data are applied to interpretation of the mechanism of the studied reactions.
Авторлар туралы
I. Shpan’ko
Donetsk National University
Хат алмасуға жауапты Автор.
Email: shpanko09@rambler.ru
Украина, ul. 600-letiya 21, Vinnitsa, 21021
I. Sadovaya
Donetsk National University
Email: shpanko09@rambler.ru
Украина, ul. 600-letiya 21, Vinnitsa, 21021