Rhodium-catalyzed alkylation of ketones and alcohols with alcohols


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Resumo

An efficient method for direct alkylation of ketones and alcohols through the borrowing hydrogen strategy in the presence of rhodium complexes as catalyst was developed. This transformation is tolerant to various functional substrates and is efficient in C–C coupling of primary and secondary alcohols, which provides an alternative method of the synthesis of functional ketones from simple and commercially available materials.

Sobre autores

X. Yu

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: wwangdawei@163.com
República Popular da China, Jiangsu Province, Wuxi, 214122

Q. Wang

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: wwangdawei@163.com
República Popular da China, Jiangsu Province, Wuxi, 214122

Q. Wu

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: wwangdawei@163.com
República Popular da China, Jiangsu Province, Wuxi, 214122

D. Wang

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Autor responsável pela correspondência
Email: wwangdawei@163.com
República Popular da China, Jiangsu Province, Wuxi, 214122


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2016

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