Email this article Rhodium-catalyzed alkylation of ketones and alcohols with alcohols
- Authors: Yu X.1, Wang Q.Y.1, Wu Q.J.1, Wang D.W.1
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Affiliations:
- The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
- Issue: Vol 86, No 1 (2016)
- Pages: 178-183
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213587
- DOI: https://doi.org/10.1134/S107036321601028X
- ID: 213587
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Abstract
An efficient method for direct alkylation of ketones and alcohols through the borrowing hydrogen strategy in the presence of rhodium complexes as catalyst was developed. This transformation is tolerant to various functional substrates and is efficient in C–C coupling of primary and secondary alcohols, which provides an alternative method of the synthesis of functional ketones from simple and commercially available materials.
Keywords
About the authors
X. Yu
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: wwangdawei@163.com
China, Jiangsu Province, Wuxi, 214122
Q. Y. Wang
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: wwangdawei@163.com
China, Jiangsu Province, Wuxi, 214122
Q. J. Wu
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: wwangdawei@163.com
China, Jiangsu Province, Wuxi, 214122
D. W. Wang
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Author for correspondence.
Email: wwangdawei@163.com
China, Jiangsu Province, Wuxi, 214122
