Synthesis and properties of tetra-(4-tert-butyl-5-nitro)phthalocyanines
- Autores: Rodionov A.1, Maizlish V.1, Shaposhnikov G.1
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Afiliações:
- Research Institute of Macroheterocycles
- Edição: Volume 86, Nº 1 (2016)
- Páginas: 96-101
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213439
- DOI: https://doi.org/10.1134/S1070363216010175
- ID: 213439
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Resumo
The interaction of 4-tert-butyl-5-nitrophthalonitrile with a series of metal acetates has yielded the corresponding metal phthalocyaninates. The treatment of magnesium tetra(4-tert-butyl-5-nitro)phthalocyaninate with hydrochloric acid has afforded tetra(4-tert-butyl-5-nitro)phthalocyanine. Spectral properties of the prepared macrocycles have been studied. The nature of the organic solvent and the complex forming metal marginally affect the position of the Q band in the electron absorption spectra of the studied compounds. It has been demonstrated that the prepared phthalocyanines can dye polymer materials and are catalytically active towards oxidation of a model sulfur-containing compound.
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Sobre autores
A. Rodionov
Research Institute of Macroheterocycles
Email: maizlish@isuct.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000
V. Maizlish
Research Institute of Macroheterocycles
Autor responsável pela correspondência
Email: maizlish@isuct.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000
G. Shaposhnikov
Research Institute of Macroheterocycles
Email: maizlish@isuct.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000