Synthesis and properties of tetra-(4-tert-butyl-5-nitro)phthalocyanines
- Authors: Rodionov A.V.1, Maizlish V.E.1, Shaposhnikov G.P.1
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Affiliations:
- Research Institute of Macroheterocycles
- Issue: Vol 86, No 1 (2016)
- Pages: 96-101
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213439
- DOI: https://doi.org/10.1134/S1070363216010175
- ID: 213439
Cite item
Abstract
The interaction of 4-tert-butyl-5-nitrophthalonitrile with a series of metal acetates has yielded the corresponding metal phthalocyaninates. The treatment of magnesium tetra(4-tert-butyl-5-nitro)phthalocyaninate with hydrochloric acid has afforded tetra(4-tert-butyl-5-nitro)phthalocyanine. Spectral properties of the prepared macrocycles have been studied. The nature of the organic solvent and the complex forming metal marginally affect the position of the Q band in the electron absorption spectra of the studied compounds. It has been demonstrated that the prepared phthalocyanines can dye polymer materials and are catalytically active towards oxidation of a model sulfur-containing compound.
Keywords
About the authors
A. V. Rodionov
Research Institute of Macroheterocycles
Email: maizlish@isuct.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
V. E. Maizlish
Research Institute of Macroheterocycles
Author for correspondence.
Email: maizlish@isuct.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
G. P. Shaposhnikov
Research Institute of Macroheterocycles
Email: maizlish@isuct.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000